Chemistry Letters p. 1025 - 1028 (1985)
Update date:2022-08-11
Topics:
Nakagawa, Nasaji
Maruki, Mitsuya
Watanabe, Ken-Ichi
Inclusion compounds of α- and β-cyclodextrins(CD) with p-nitrobenzaldehyde were prepared.They underwent the aldol reactions with acetone in the presence of Zn2+ complexes of L-tyrosine ester to afford an enantiomeric excess aldol-type product.The reactions of the β-CD compound were superior to that of the α-CD one both in reactivity and asymmetric induction.
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