Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1845 - 1847 (1989)
Update date:2022-08-30
Topics:
Kuptsova, T. S.
Buravtsev, N. N.
Chernyak, N. Ya.
Shapiro, E. A.
Kolbanovskii, Yu. A.
Nefedov, O. M.
The thermal isomerization of 3,3-dimethylcyclopropene under adiabatic-compression conditions at 660-850 K occurs in two independent directions with the formation of isopropylacetylene and isoprene; kinetic parameters for each of these routes were obtained.The formation of products of the gem-dimethylvinylcyclopropanation of olefins during their copyrolysis with 3,3-dimethylcyclopropene is not observed, apparently because of the occurrence of isomerization of 3,3-dimethylcyclopropene in the gas phase at 660-850 K without the participation of gem- dimethylvinylcarbene.
View More
Nanjing Habo Medical Technology Co., Ltd.
Contact:025－85769882
Address:No.108. Ganjiabian east. Qixia District .Nanjing
Nanjing lanbai chemical Co.,Ltd.
Contact:+86-25-85499326
Address:Room 908, 9F Taiyue Building,No.285 Heyan Road
Hangzhou Taiyan Trading Co., Ltd(expird)
Contact:+86-13777583958
Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China
Anhui Sholon New Material Technology Co., Ltd.
website:http://www.sholonchem.com
Contact:+86-550-5261666
Address:4/F Block B, Beijing Chemical Building.No.520 Tianrun Road ,Science & Education Town Wujin District, Changzhou City Jiangsu Province
Shenzhen Sunrising Industry Co., ltd.
Contact:+86 755 86571158 / 86571159 / 86571160
Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Doi:10.3987/COM-03-9957
(2004)Doi:10.1016/j.tetlet.2015.12.101
(2016)Doi:10.1039/b400198b
(2004)Doi:10.1021/jo00813a044
(1971)Doi:10.1016/S0968-0896(00)00127-9
(2000)Doi:10.1080/10426500490474842
(2004)
