Evidence for a Concerted SN2' Mechanism in the Gas-Phase Acid-induced Nucleophilic Substitutions on Allylic Substrates

DOI: 10.1039/c39950000547

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 547 - 548 (1995)

Update date:2022-08-10

Topics:

Authors:

Dezi, Emanuela

Lombardozzi, Antonietta

Pizzabiocca, Adriano

Renzi, Gabriele

Speranza, Maurizio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950000547

Gas phase nucleophilic substitution on oxygen-protonated but-1-en-3-ol and trans-but-2-en-1-ol by methanol proceeds via the concerted S_N2' mechanism in competition with the classical S_N2 mechanism.

Full text of DOI:10.1039/c39950000547

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3-Buten-2-ol

Cas No:598-32-3

R&D Labs maybe for 598-32-3

Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China
Shaanxi HuaTai Bio-fine chemical company Ltd

Contact:86-029-87862197

Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Xinjiang Zhongtai Chemical Co., Ltd.

Contact:+86-991-8788172

Address:NO.78 XISHAN RD.URUMQI，CHINA
Hangzhou Haiqiang Chemical Co.,Ltd.

Contact:+86-571-86960370

Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING

Relevant to this article

Thermodynamics of sublimation and solvation for bicyclo-derivatives of 1,3-thiazine

Doi:10.1016/j.tca.2013.07.005
(2013)
Stereocontrol by intrinsic antiparallel double repulsion on diacetone-D-glucose template. Diastereoselective synthesis of 3(S)-isothiocyanato-3-deoxy-3-C-vinyl glucose via (3,3)-sigmatropic rearrangement of allylic thiocyanates

Doi:10.1016/S0040-4039(97)01246-X
(1997)
A Facile Reduction of Azides to Amines Using Hydrazine

Doi:10.1055/s-1989-27284
(1989)
Synthesis of 4-chalcogenyl pyrazoles via electrophilic chalcogenation/cyclization of α,β-alkynic hydrazones

Doi:10.1039/d0ob00050g
(2020)
E-senegasaponins a and b, Z-senegasaponins a and b, Z-senegins II and III, new type inhibitors of ethanol absorption in rats from Senegae Radix, the roots of Polygala senega L. Var latifolia Torrey et Gray

Doi:10.1248/cpb.43.350
(1995)
Photolysis of matrix-isolated CF₃C(O)SH and CF₃C(O)SCl

Doi:10.1016/S0022-2860(96)09639-1
(1997)

Article Doi