Journal of the Chemical Society. Perkin transactions II p. 403 - 408 (1982)
Update date:2022-08-17
Topics:
Bowen, Richard D.
The slow unimolecular reactions of metastable CH3CH2CH=N(+)HCH3 and (CH3)2C=N(+)HCH3 ions are reported and discussed.Details of the mechanisms of these reactions are elucidated by 2H-labelling studies.Loss of C3H6 from these C4H10N(+) ions shown to occur after irreversible isomerisation to CH3CH2CH2N(+)H=CH2 and related structures.The behaviour of CH3CH2CH=N(+)HCH3 and (CH3)2C=N(+)HCH3 is compared with that of the lower homologues
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