Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 646 - 650 (1990)
Update date:2022-08-17
Topics:
Meskina, M. Ya.
Baider, L. M.
Skibida, I. P.
Kinetic investigation of the reaction of electrochemically generated O2.- with perfluorooctene, styrene, and cyclohexene in acetonitrile, in the presence of tetraethylammonium perchlorate used as a background electrolyte, revealed that O2.- reacts with styrene and perfluorooctene at the double bond, and the reactivity of the olefins with respect to O2.- decreases with decrease in the electrophilicity of the substituents at the double bond: perfluorooctene > styrene > cyclohexene.The main transformation products of styrene are phthalic and benzoic acid esters.
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