Journal of the Chemical Society. Chemical communications p. 1127 - 1129 (1986)
Update date:2022-08-28
Topics:
Farras, Jaume
Vilarrasa, Jaume
Treatment of 4,5-dicyano-2-diazoimidazole, 2-diazoimidazole, amd 3-diazopyrazole with 1,1-dimethoxyethene affords azolo-as-triazines (1c), (3c), and (8c), respectively; the involvement as intermediates of either aziridines (d), arising from a 'nitrene-like reaction' of diazoazoles, or azoalkenes (b) should be questioned at present.
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