Bulletin of the Chemical Society of Japan p. 2241 - 2246 (1986)
Update date:2022-08-11
Topics:
Yamamoto, Shunzo
Ishikawa, Yo-ichi
Arai, Shigeyoshi
The infrared multiple-photon decomposition of β-propiolactone was found to give only ethylene and carbon dioxide with the same yield as the products, where the material balance was above 90percent.This result suggests that the unimolecular decomposition into ethylene and carbon dioxide is a unique reaction channel of the compound at highly vibrationally excited states.It was shown that the decomposition probability was strongly dependent on the fluence but slightly dependent on the pressure.
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