Regio- and Stereoselective Samarium Diiodide-Promoted Intermolecular Coupling between Vinyloxiranes and Ketones. Synthesis of 2-Alken-1,5-Diols

DOI: 10.1016/0040-4039(95)01416-F

Source and publish data:

Tetrahedron Letters p. 7129 - 7132 (1995)

Update date:2022-08-16

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Authors:

Aurrecoechea, Jose M.

Iztueta, Elena

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Article abstract of DOI:10.1016/0040-4039(95)01416-F

Reduction of vinyloxiranes with SmI2-HMPA at low temperatures in the presence of ketones results in the efficient formation of 2-alken-1,5-diols with predominant or exclusive (E) configuration.In the absence of HMPA higher temperatures are needed for the

Full text of DOI:10.1016/0040-4039(95)01416-F

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