Biomimetic synthesis of Nauclea indole alkaloids, naucleidinal, and 3- epi-naucleidinal, by stereoselective rearrangement of strictosamide and the vincoside lactam aglycones

DOI: 10.1248/cpb.44.2192

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2192 - 2194 (1996)

Update date:2022-08-23

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Authors:

Takayama, Hiromitsu

Miyabe, Yuhko

Shito, Toshiaki

Kitajima, Mariko

Aimi, Norio

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Article abstract of DOI:10.1248/cpb.44.2192

Based on a biogenetic consideration, a Nauclea alkaloid, naucleidinal (6), and its 3-epimer (7) were stereoselectively prepared from the aglycones of strictosamide and the vincoside lactam, and their absolute stereochemistry was confirmed.

Full text of DOI:10.1248/cpb.44.2192

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