Journal of Physical Chemistry p. 3674 - 3678 (1981)
Update date:2022-08-11
Topics:
Kurylo, Michael J.
Klais, Odo
Laufer, Allan H.
A steady-state photolysis experiment including mass-spectrometric end-product analysis was used to conduct a mechanistic investigation of the H(18)O+HO2 reaction system.The results obtained do not support the existence of a linear adduct reaction intermediate as suggested by a proposed pressure dependennce for the title reaction: HO+HO2->H2O+O2 (k1).An elaborate modeling analysis of the experiment best matches the observed product yields for values of k1 in the range 1*10-10-2*10-10 cm3 molecule-1 s-1.
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