Journal of the Chemical Society. Chemical communications p. 1504 - 1505 (1986)
Update date:2022-08-24
Topics:
Kitajima, Nobumasa
Whang, Kaehong
Moro-oka, Yoshihiko
Uchida, Akira
Sasada, Yoshio
N,N'-(2-Hydroxy-propane-1,3-diyl)bis(salicylaldiminato)copper(II) was found to be an effective catalyst for the oxidation of ethanol, n-propanol, or hydroxyacetone in the presence of KOH under O2; the X-ray crystal structure shows that the co-ordination geometry of the copper is significantly distorted toward tetrahedral from square planar with two oxygens and two nitrogens from salicylaldimine moieties.
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