Journal of the Chemical Society. Chemical communications p. 360 - 361 (1983)
Update date:2022-08-22
Topics:
Carruthers, William
Cumming, S. Andrew
Palladium(0)-catalysed cyclisation of 3-acetoxy-1-(4-aminoalkyl)cyclohexenes provides easy access to the 1-azaspiro<5.5>undecane ring system found in the histrionicotoxins; this has been exploited in a synthesis of (+/-)-depentylperhydrohistrionicotoxin.
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