Tetrahedron Letters p. 1087 - 1090 (1996)
Update date:2022-08-03
Topics:
Grice, I. Darren
Harvey, Peta J.
Jenkins, Ian D.
Gallagher, Michael J.
Ranasinghe, Millagahamada G.
Treatment of a dialkyl phosphite with triphenylphosphine and diisopropyl azodicarboxylate in toluene, followed by addition of an alcohol, results in the formation of the corresponding trialkyl phosphite. Similarly, dialkyl phosphonites can be synthesised from monoalkyl phosphites (alkyl phosphinates).
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