8-Hydroxy-2′-deoxyguanosine formation and DNA damage induced by a dinuclear manganese(IV) complex and hydrogen peroxide

DOI: 10.1039/DT9960002391

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2391 - 2392 (1996)

Update date:2022-08-17

Topics:

Authors:

Kobayashi, Teruyuki

Tsuchiya, Kazuyoshi

Nishida, Yuzo

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Article abstract of DOI:10.1039/DT9960002391

The dinuclear manganese(IV) complex [Mn₂O₃L₂][PF₆]₂ exhibits high activity for 8-hydroxy-2′-deoxyguanosine formation and relaxation of pBR322 form I DNA in the presence of H₂O₂, where L = 1,4,7-trimethyl-1,4,7-triazacyclononane; the active species is postulated to be a unidentate peroxide adduct of the manganese(IV) complex.

Full text of DOI:10.1039/DT9960002391

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