Journal of the Chemical Society, Dalton Transactions p. 2391 - 2392 (1996)
Update date:2022-08-17
Topics:
Kobayashi, Teruyuki
Tsuchiya, Kazuyoshi
Nishida, Yuzo
The dinuclear manganese(IV) complex [Mn2O3L2][PF6]2 exhibits high activity for 8-hydroxy-2′-deoxyguanosine formation and relaxation of pBR322 form I DNA in the presence of H2O2, where L = 1,4,7-trimethyl-1,4,7-triazacyclononane; the active species is postulated to be a unidentate peroxide adduct of the manganese(IV) complex.
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