Chemistry Letters p. 857 - 858 (1997)
Update date:2022-08-11
Topics:
Bottle, Steven E.
Chand, Ugesh
Micallef, Aaron S.
The photochemical! y excited nitroxide, 1,1,3,3-tetramethylisoindolin-2-yloxyl (1*), abstracts primary, secondary or tertiary hydrogens from unactivated hydrocarbons including cyclohexane, isobutane and n-butane. The resultant carbon-centred radicals are rapidly and efficiently trapped by ground state nitroxide. Hydrogen abstraction from methane may also occur, but is masked by secondary photochemical reactions.
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