Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Sulfur dichloride

Related Products

Hot Products

Name

Sulfur dichloride

EINECS 234-129-0
CAS No. 10545-99-0 Density 1.577 g/cm3
PSA 25.30000 LogP 2.02720
Solubility Soluble in tetrachloromethane, benzene and n-hexane, decompose in water Melting Point -78 °C
Formula Cl2S Boiling Point 59 °C
Molecular Weight 102.972 Flash Point N/A
Transport Information UN 3390 6.1/PG 1 Appearance Dark red or faint red liquid
Safety 26-27-28-36/37/39-45-61 Risk Codes 23/24/25-40-50-37-14-35
Molecular Structure Molecular Structure of 10545-99-0 (Sulfur dichloride) Hazard Symbols ToxicT, DangerousN, CorrosiveC
Synonyms

Chlorinesulfide;Dichlorosulfane;Dichlorosulfur;Monosulfur dichloride;Sulfurchloride;Sulfur chloride;

Article Data 117

Sulfur dichloride Synthetic route

thiodiazyl dichloride

7782-50-5

chlorine

B

10545-99-0

sulfur dichloride

Conditions
ConditionsYield
A 88%
B n/a
7704-34-9

sulfur

10025-68-0

diselenium dichloride

A

10025-67-9

disulfur dichloride

B

1087399-32-3

sulfur selenium dichloride

C

10545-99-0

sulfur dichloride

D

10026-03-6

selenium tetrachloride

Conditions
ConditionsYield
In neat (no solvent) heating of equimolar amount in closed tube to 200°C for 6 h;; fractional distillation;;A n/a
B 30%
C n/a
D n/a
In neat (no solvent) heating of equimolar amount in closed tube to 200°C for 6 h;; fractional distillation;;A n/a
B 30%
C n/a
D n/a
In neat (no solvent) heating of equimolar amount in closed tube to 100, 150, 200 or 250°C for 6 h;; fractional distillation;;
In neat (no solvent) heating of equimolar amount in closed tube to 100, 150, 200 or 250°C for 6 h;; fractional distillation;;
10025-67-9

disulfur dichloride

7782-49-2

selenium

A

selenium sulfur dichloride

B

10545-99-0

sulfur dichloride

C

10026-03-6

selenium tetrachloride

Conditions
ConditionsYield
In neat (no solvent) heating in closed tube to 200°C for 4 h;; fractional distillation;;A 13.2%
B n/a
C n/a
In neat (no solvent) heating in closed tube to 200°C for 4 h;; fractional distillation;;A 13.2%
B n/a
C n/a
In neat (no solvent) heating in closed tube at 100, 150, 200 or 250°C for 4 h;; fractional distillation;;
In neat (no solvent) heating in closed tube at 100, 150, 200 or 250°C for 4 h;; fractional distillation;;
75-15-0

carbon disulfide

A

17494-65-4

dichloromethanebis(sulphenyl chloride)

B

10545-99-0

sulfur dichloride

C

594-42-3

chlorothio-trichloro-methane

Conditions
ConditionsYield
With chlorine at -20 - -5℃; for 2.5h; Irradiation; Yields of byproduct given;A 1.58%
B n/a
C n/a
With chlorine at -20 - -5℃; for 2.5h; Irradiation; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

barium hypochlorite

sodium thiosulfate

A

barium sulfate

B

barium thiosulfate

C

10545-99-0

sulfur dichloride

D

16887-00-6

chloride

E

tetrathionate(2-)

Conditions
ConditionsYield
In not given molar ratio of Ba(OCl)2:Na2S2O3=2:1, warmed;

iron sulfide

7782-50-5

chlorine

A

10545-99-0

sulfur dichloride

B

7705-08-0

iron(III) chloride

Conditions
ConditionsYield
In neat (no solvent) at ambient temp. and 4000 Torr;;A n/a
B >99

mercury sulfide

7782-50-5

chlorine

A

10025-67-9

disulfur dichloride

B

10545-99-0

sulfur dichloride

C

mercury dichloride

Conditions
ConditionsYield
below 200°C;; almost pure;;A n/a
B n/a
C >99
10025-67-9

disulfur dichloride

7446-11-9

sulfur trioxide

7782-50-5

chlorine

A

7719-09-7

thionyl chloride

B

10545-99-0

sulfur dichloride

Conditions
ConditionsYield
In neat (no solvent) 100-110°C; iron reactor, presence of SbCl3;; distillation over S (formation of educt S2Cl2 from SCl2);;
7719-09-7

thionyl chloride

7439-95-4

magnesium

A

10545-99-0

sulfur dichloride

B

sulfur monoxide

Conditions
ConditionsYield
Formation of spectroscopic detectable amounts of SO.;

vanadia

7782-50-5

chlorine

7704-34-9

sulfur

A

10025-67-9

disulfur dichloride

B

10545-99-0

sulfur dichloride

C

7632-51-1

vanadiumtetrachloride

D

7727-18-6

vanadium(V) oxychloride

Conditions
ConditionsYield
In neat (no solvent) heating;;

Sulfur dichloride Specification

Sulfur dichloride is an organic compound with the formula Cl2S, and its systematic name is the same with the product name. With the CAS registry number 10545-99-0, it is also named as Monosulfur dichloride. It belongs to the product category of Inorganics. Its EINECS number is 234-129-0. In addition, the molecular weight is 102.97. It should be sealed and stored in a cool, ventilated and dry place. Moreover, it should be protected from oxides, heat and fire.

Physical properties of Sulfur dichloride are: (1)ACD/LogP: 1.335; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.34; (4)ACD/LogD (pH 7.4): 1.34; (5)ACD/BCF (pH 5.5): 6.09; (6)ACD/BCF (pH 7.4): 6.09; (7)#H bond acceptors: 0; (8)#H bond donors: 0; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 25.3 Å2; (11)Index of Refraction: 1.516; (12)Molar Refractivity: 19.744 cm3; (13)Molar Volume: 65.274 cm3; (14)Polarizability: 7.827×10-24cm3; (15)Surface Tension: 35.83 dyne/cm; (16)Density: 1.578 g/cm3.

Preparation: it is produced by the chlorination of either elemental sulfur or disulfur dichloride. The process occurs in a series of steps. S2Cl2 is the most common impurity in SCl2. Separation of SCl2 from S2Cl2 is possible via distillation with PCl3 to form an azeotrope of 99% purity, however sulfur dichloride loses chlorine slowly at room temperature and reverts to disulfur dichloride. Pure samples may be stored in sealed glass ampules which develop a slight positive pressure of chlorine, halting the decomposition.

S8 + 4 Cl2 → 4 S2Cl2

S2Cl2 + Cl2 → 2 SCl2

Uses of Sulfur dichloride: it is used in organic synthesis. It adds to alkenes to give chloride-substituted thioethers. It is also a precursor to several inorganic sulfur compounds. Moreover, it is used as chlorinating agent in organic synthesis, and it is also used as annexing agent of cutting oil. It can be used as a disinfectant and fungicide.

When you are using this chemical, please be cautious about it as the following:
This chemical will react violently with water. It is toxic by inhalation, in contact with skin and if swallowed, and is irritating to respiratory system. Moreover, it is very toxic to aquatic organisms. This chemical can cause severe burns. It has a limited evidence of a carcinogenic effect. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. After contact with skin, you need to wash immediately with plenty of ... (to be specified by the manufacturer). When using it, you need to wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible). You must take off immediately all contaminated clothing. You should avoid releasing it to the environment, and you need to refer to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: ClSCl
(2)Std. InChI: InChI=1S/Cl2S/c1-3-2
(3)Std. InChIKey: FWMUJAIKEJWSSY-UHFFFAOYSA-N 

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 10545-99-0