Products Categories
Basic Information
| CAS No.: | 593-74-8 |
|---|---|
| Name: | DIMETHYLMERCURY |
| Molecular Structure: | |
|
|
|
| Formula: | C2H6 Hg |
| Molecular Weight: | 230.66 |
| Synonyms: | Dimethylmercury |
| EINECS: | 209-805-3 |
| Density: | 2.961 g/mL at 25 °C(lit.) |
| Melting Point: | ?43 °C(lit.) |
| Boiling Point: | 93-94 °C(lit.) |
| Flash Point: | 42 °c |
| Solubility: |
Stability
Toxicology
|
| Appearance: | Colorless liquid |
| Hazard Symbols: |
 T+ N
|
| Risk Codes: | 26/27/28-33-50/53 |
| Safety: | Suspected carcinogen. Highly toxic. Mutation data reported. Easily flammable. When heated to decomposition it emits toxic fumes of Hg. |
| Transport Information: | UN 3383 |
| PSA: | 0.00000 |
| LogP: | 1.16510 |
Related products
- 81281-59-67-Benzylideneaminotheophylline
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 68439-39-4Poly(oxy-1,2-ethanediyl), alpha-(2-ethylhexyl)-omega-hydroxy-,
- 852475-26-4MC1568
- 958254-66-51H-Imidazo[4,5-b]pyridine-2-carboxaldehyde, 1-methyl-, hydrochloride
- 99170-93-1N-Methyl-2-oxazolamine
- 717878-06-31-(4-fluorophenyl)-4-nitro-1H-imidazole
- 914458-26-7[5-(2-fluorophenyl)-1-pentyl-1H-pyrrol-3-yl]-1-naphthalenyl-Methanone
- 894852-01-87-BROMO-2,2-DIMETHYL-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
Synthetic route
- 587-85-9
diphenylmercury(II)
- 1445-79-0
trimethyl gallium
A
- 1059626-80-0
methyl(diphenyl)gallium
B
- 593-74-8
dimethylmercury
Conditions
| Conditions | Yield |
|---|---|
| In neat (no solvent) (CH3)3Ga was added to freshly sublimed diphenylmercury, the suspn. was heated at 100°C in a closed vessel for 3 h, cooled to room temp. without stiring; volatiles were removed in vac. (1E-2 mbar), crystals were washed with n-hexane and dried in vac. for 2 h: elem. anal.; | A 98% B n/a |
...Expand
- 371-76-6
bis(trifluoromethyl)mercury
- 75-74-1
Tetramethylblei-(IV)
A
- 593-74-8
dimethylmercury
B
- 33327-63-8
methyl(trifluoromethyl)mercury
C
- 646-62-8
trimethyl(trifluoromethyl)lead
Conditions
| Conditions | Yield |
|---|---|
| In toluene absence of air and moisture; heating of PbMe4 with two-fold excess of Hg-compd. (sealed tube, 70°C, 2 weeks); gas chromy.; | A 2% B 94% C 93% |
...Expand
- 587-85-9
diphenylmercury(II)
- 1445-79-0
trimethyl gallium
A
- 1059626-77-5
dimethyl(phenyl)gallium
B
- 593-74-8
dimethylmercury
Conditions
| Conditions | Yield |
|---|---|
| In neat (no solvent) in an Schlenk flask (CH3)3Ga was added to freshly sublimed (C6H5)2Hg, the vessel was tightly closed, the suspn. was heated at 100°C for 5h, cooled to room temp.; volatiles were removed under reduced pressure (10 mbar), the residue waswashed twice with n-hexane at -70°C; elem. anal.; | A 90% B n/a |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: methylchloride; 23°C, 12 equiv of methylmagnesiumchloride; | A 85% B n/a |
...Expand
- 75535-77-2
[(C5H5)2Ti(C6H5)(CH3)]
- 115-09-3
methylmercury(II) chloride
A
- 1278-83-7
bis(cyclopentadienyl)methyltitanium(IV) chloride
C
- 593-74-8
dimethylmercury
D
- 21392-61-0
methyl phenyl mercury
Conditions
| Conditions | Yield |
|---|---|
| In [(2)H6]acetone to cold (-78 °C) soln. of Ti complex (excess) in acetone-d6 added soln. of MeHgCl in acetone-d6 under N2, stirred at -78 °C for 2h, stirred at room temp. for 6 h; monitored by NMR; | A 40% B 60% C 60% D 40% |
...Expand
- 1451001-55-0
1-(2-hydroxyethyl)-3-methyl-(1H)-imidazole-2(3H)-selone
- 115-09-3
methylmercury(II) chloride
B
- 593-74-8
dimethylmercury
Conditions
| Conditions | Yield |
|---|---|
| In water; acetonitrile at 23℃; for 168h; Kinetics; Schlenk technique; | A 53% B n/a |
...Expand
A
- 70-18-8
GLUTATHIONE
C
- 593-74-8
dimethylmercury
D
- 2033-53-6
1-(2-hydroxyethyl)-3-methyl-1H-benzo[d]imidazol-2(3H)-one
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: methylmercury-L-glutathionate; 1-(2-hydroxyethyl)-3-methyl-1H-benzo[d]imidazole-2(3H)-thione In water; acetonitrile at 37℃; for 1h; Stage #2: With sodium hydrogencarbonate In water; acetonitrile at 37℃; for 5h; | A n/a B 11 mg C n/a D 40% |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With sodium amalgam; acetic acid methyl ester at -5 - -3℃; |
Conditions
| Conditions | Yield |
|---|---|
| With diethyl ether; mercury dichloride |
Conditions
| Conditions | Yield |
|---|---|
| With mercury |
Hot Products
- 7790-28-5Periodicacid (HIO4), sodium salt (1:1)
- 80-05-7Bisphenol A
- 61789-80-8Dimethyl di(hydrogenated tallow) ammonium chloride
- 61-52-91H-Indole-3-ethanamine,N,N-dipropyl-
- 42017-89-0Fenofibric acid
- 106-43-44-Chlorotoluene
- 10026-04-7Silane, tetrachloro-
- 68140-00-1Coconut oil monoethanolamide
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
Post a RFQ
1
What can I do for you?
Get Best Price
Get Best Price for 593-74-8
DIMETHYLMERCURY
Chemistry
Molecular formula C2H6Hg
Molar mass 230.659 g/mol
Appearance Colorless liquid
Density 2.96 g/ml, liquid
Melting point -43 °C
Boiling point 87 - 97 °C
Solubility in water Insoluble
Molar mass 230.659 g/mol
Appearance Colorless liquid
Density 2.96 g/ml, liquid
Melting point -43 °C
Boiling point 87 - 97 °C
Solubility in water Insoluble
Uses
Dimethylmercury is most often used in toxicology experiments as a fixed point of reference due to its extreme toxicity. It has also been used to calibrate NMR instruments for detection of mercury, although less toxic mercury salts are preferred.
Toxicity Data With Reference
| 1. | dnd-mmo-omi 600 mg/L | NATUAS Nature. 257 (1975),422. | ||
| 2. | oth-mus:oth 25 mg/L | MUREAV Mutation Research. 17 (1973),93. |
Consensus Reports
IARC Cancer Review: Group 2B IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 239.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 239.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory.
Safety Profile
Suspected carcinogen. Highly toxic. Mutation data reported. Easily flammable. When heated to decomposition it emits toxic fumes of Hg.
Hazard Codes T+,N
Risk Statements 26/27/28-33-50/53
Safety Statements 13-28-36-45-60-61
RIDADR UN 3383 6.1/PG 1
HazardClass 3.1
WGK Germany 3
Hazard Codes T+,N
Risk Statements 26/27/28-33-50/53
Safety Statements 13-28-36-45-60-61
RIDADR UN 3383 6.1/PG 1
HazardClass 3.1
WGK Germany 3
Standards and Recommendations
OSHA PEL: TWA 0.01 mg(Hg)/m3; CL 0.03 mg(Hg)/m3 (skin)
ACGIH TLV: TWA 0.01 mg(Hg)/m3; BEI: 35 μg/g creatinine total inorganic mercury in urine preshift; 15 μg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
ACGIH TLV: TWA 0.01 mg(Hg)/m3; BEI: 35 μg/g creatinine total inorganic mercury in urine preshift; 15 μg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans