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62147-49-3
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Basic Information
CAS No.: 62147-49-3
Name: 2,5-Dihydroxy-1,4-dioxane-2,5-dimethanol
Molecular Structure:
Molecular Structure of 62147-49-3 (2,5-Dihydroxy-1,4-dioxane-2,5-dimethanol)
Formula: C6H12 O6
Molecular Weight: 180.158
Synonyms: 1,4-Dioxane-2,5-dimethanol,2,5-dihydroxy-, trans-
EINECS: 202-494-5
Density: 1.546 g/cm3
Melting Point: 70.00 - 80.00 ºC
Boiling Point: 448 °C at 760 mmHg
Flash Point: 224.7 °C
Solubility: Soluble in ethanol, ethyl ether, acetone. Slightly soluble in water. Insoluble in ligroin.
Appearance: white to off-white crystalline powder
Hazard Symbols:
Risk Codes: R36/37/38   
Safety: 26-36
PSA: 99.38000
LogP: -2.60500
Related products
Synthetic route
56-81-5

glycerol

62147-49-3

1,3-dihydroxyacetone dimer

Conditions
ConditionsYield
With C32H30N4O4Pd2(2+); p-benzoquinone In water; acetonitrile at 23℃; for 4h;58%
50-00-0

formaldehyd

A

62147-49-3

1,3-dihydroxyacetone dimer

B

40031-31-0

erythrulose

C

50-69-1, 58-86-6, 65-42-9, 147-81-9, 609-06-3, 1114-34-7, 1949-78-6, 5328-37-0, 10323-20-3, 20235-19-2, 24259-59-4, 25990-60-7, 34466-20-1, 41247-05-6, 53106-52-8, 55058-43-0, 80952-57-4

arabinose

D

50-69-1, 58-86-6, 65-42-9, 147-81-9, 609-06-3, 1114-34-7, 1949-78-6, 5328-37-0, 10323-20-3, 20235-19-2, 24259-59-4, 25990-60-7, 34466-20-1, 41247-05-6, 53106-52-8, 55058-43-0, 80952-57-4

xylose

E

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

galactose

F

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

glucose

Conditions
ConditionsYield
With triethylamine; thiazolium salt In N,N-dimethyl-formamide at 100℃; Mechanism; Product distribution; influence of amount of paraformaldehyde, paraformaldehyde:catalyst ratio, reaction temperature and time, other amine bases;
...Expand
50-00-0

formaldehyd

A

62147-49-3

1,3-dihydroxyacetone dimer

B

40031-31-0

erythrulose

C

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

galactose

D

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

glucose

Conditions
ConditionsYield
With triethylamine; 3-benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazol-3-ium chloride In N,N-dimethyl-formamide at 100℃; Further byproducts given;
...Expand
50-00-0

formaldehyd

A

62147-49-3

1,3-dihydroxyacetone dimer

B

50-69-1, 58-86-6, 65-42-9, 147-81-9, 609-06-3, 1114-34-7, 1949-78-6, 5328-37-0, 10323-20-3, 20235-19-2, 24259-59-4, 25990-60-7, 34466-20-1, 41247-05-6, 53106-52-8, 55058-43-0, 80952-57-4

arabinose

C

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

galactose

D

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

glucose

Conditions
ConditionsYield
With triethylamine; 3-benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazol-3-ium chloride In N,N-dimethyl-formamide at 100℃; Further byproducts given;
...Expand
50-00-0

formaldehyd

A

62147-49-3

1,3-dihydroxyacetone dimer

B

50-69-1, 58-86-6, 65-42-9, 147-81-9, 609-06-3, 1114-34-7, 1949-78-6, 5328-37-0, 10323-20-3, 20235-19-2, 24259-59-4, 25990-60-7, 34466-20-1, 41247-05-6, 53106-52-8, 55058-43-0, 80952-57-4

xylose

C

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

galactose

D

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

glucose

Conditions
ConditionsYield
With triethylamine; 3-benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazol-3-ium chloride In N,N-dimethyl-formamide at 100℃; Further byproducts given;
...Expand
50-00-0

formaldehyd

A

62147-49-3

1,3-dihydroxyacetone dimer

B

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

galactose

C

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

glucose

D

95-43-2, 95-44-3, 533-49-3, 583-50-6, 1758-51-6, 7558-94-3, 29825-68-1, 29884-64-8, 38982-45-5

threose

Conditions
ConditionsYield
With triethylamine; 3-benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazol-3-ium chloride In N,N-dimethyl-formamide at 100℃; Further byproducts given;
...Expand
50-00-0

formaldehyd

A

62147-49-3

1,3-dihydroxyacetone dimer

B

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

galactose

C

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

glucose

D

95-43-2, 95-44-3, 533-49-3, 583-50-6, 1758-51-6, 7558-94-3, 29825-68-1, 29884-64-8, 38982-45-5

erythrose

Conditions
ConditionsYield
With triethylamine; 3-benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazol-3-ium chloride In N,N-dimethyl-formamide at 100℃; Further byproducts given;
...Expand
141-46-8

Glycolaldehyde

A

62147-49-3

1,3-dihydroxyacetone dimer

B

40031-31-0

erythrulose

C

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

galactose

D

50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5

glucose

Conditions
ConditionsYield
With triethylamine; 3-benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazol-3-ium chloride In N,N-dimethyl-formamide at 60℃; for 1h; Further byproducts given;
...Expand
50-99-7

D-glucose

A

98-01-1

furfural

B

62147-49-3

1,3-dihydroxyacetone dimer

C

56-82-6

Glyceraldehyde

Conditions
ConditionsYield
With niobium(V) oxide at 20℃; for 2h; Reagent/catalyst;
...Expand
58-86-6

D-xylose

A

98-01-1

furfural

B

62147-49-3

1,3-dihydroxyacetone dimer

C

56-82-6

Glyceraldehyde

Conditions
ConditionsYield
With erbium(III) oxide at 20℃; for 2h;
...Expand
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Chemistry

IUPAC Name: 2,5-bis(hydroxymethyl)-1,4-dioxane-2,5-diol 
Empirical Formula: C6H12O6
Molecular Weight: 180.1559g/mol
EINECS: 202-494-5 
Structure of 1,4-Dioxane-2,5-dimethanol,2,5-dihydroxy-, (2R,5S)-rel- (CAS NO.62147-49-3):

Index of Refraction: 1.549
Molar Refractivity: 37.1 cm3
Molar Volume: 116.5 cm3
Polarizability: 14.71×10-24cm3
Surface Tension: 84.9 dyne/cm
Density: 1.546 g/cm3
Flash Point: 224.7 °C
Enthalpy of Vaporization: 81.51 kJ/mol 
Melting Point: 75-80 °C(lit.)
Boiling Point: 448 °C at 760 mmHg
Vapour Pressure: 6.59E-10 mmHg at 25°C 
Sensitive: Hygroscopic 
Stability: Stable. Incompatible with strong oxidizing agents. Protect from moisture. 
Physical Appearance: Off-whitepowde
Product Categories: Dioxanes;Dioxanes & Dioxolanes 
Canonical SMILES: C1C(OCC(O1)(CO)O)(CO)O
InChI: InChI=1S/C6H12O6/c7-1-5(9)3-12-6(10,2-8)4-11-5/h7-10H,1-4H2
InChIKey: KEQUNHIAUQQPAC-UHFFFAOYSA-N

Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
WGK Germany: 3
RTECS: UC1645000

Specification

  1,4-Dioxane-2,5-dimethanol,2,5-dihydroxy-, (2R,5S)-rel- , its cas register number is 62147-49-3. It also can be called 1,3-Dihydroxyacetone Dimer ; 2,5-Bis(hydroxymethyl)-1,4-dioxane-2,5-diol ; 2,5-Dihydroxy-1,4-dioxane-2,5-dimethanol ; 2,5-Dihydroxydioxane-2,5-dimethanol . 1,4-Dioxane-2,5-dimethanol,2,5-dihydroxy-, (2R,5S)-rel- (CAS NO.62147-49-3) is irritating to eyes, respiratory system and skin.