62147-49-3Relevant articles and documents
Fructose conversion in the presence of Sn(iv) catalysts exhibiting high selectivity to lactic acid
Dos Santos, Jailma Barros,De Albuquerque, Nilson José Araújo,De Paiva E Silva Zanta, Carmen Lúcia,Meneghetti, Mario Roberto,Meneghetti, Simoni Margareti Plentz
, p. 90952 - 90959 (2015/11/11)
The catalytic performance of a series of Sn(iv)-based organometallic complexes in fructose conversion was studied under several reaction conditions, and the conversion, yields, and selectivity measurements of this transformation have been evaluated. The results were compared to those obtained from non-catalysed reactions and those in the presence of a conventional catalyst (H2SO4). These organometallic Sn(iv)-based catalysts demonstrated the ability to fully convert fructose into valuable chemicals. Under particular reaction conditions, lactic acid is obtained in good yields and selectivity.
Selective catalytic oxidation of glycerol to dihydroxyacetone
Painter, Ron M.,Pearson, David M.,Waymouth, Robert M.
supporting information; experimental part, p. 9456 - 9459 (2011/03/19)
High selectivity and high yield characterize the oxidation of glycerol into dihydroxyacetone using catalyst 1, with benzoquinone or air as the oxidant. The mechanism proposed involves reversible palladium-alkoxide formation with the turnover-limiting reoxidation of the palladium complex. Copyright
