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58-86-6

Basic Information
CAS No.: 58-86-6
Name: D(+)-Xylose
Article Data: 433
Cas Database
Molecular Structure:
Molecular Structure of 58-86-6 (D(+)-Xylose)
Formula: C5H10O5
Molecular Weight: 150.131
Synonyms: Xylose, D-(8CI);(+)-Xylose;D-(+)-Xylose;Wood sugar;
EINECS: 200-400-7
Density: 1.525
Melting Point: 154-158°C(lit.)
Boiling Point: 331oC
Flash Point: 219.2oC
Solubility: soluble
Appearance: White crystal powder
Hazard Symbols: Xi
Risk Codes: 36/37/38
Safety: 24/25-36-26
Transport Information: N/A
PSA: 90.15000
LogP: -2.58230
Synthetic route
xylan

xylan

58-86-6

D-xylose

Conditions
ConditionsYield
With hydrogenchloride; water at 105℃; for 3h; Ionic liquid;77%
With water at 60℃; for 3h;73 %Chromat.
xylan

xylan

A

58-86-6

D-xylose

B

1114-34-7

D-lyxose

Conditions
ConditionsYield
With hydrogenchloride; sodium molybdate dihydrate In water for 0.05h; Sealed tube; Microwave irradiation;A 60%
B 31%
xylan

xylan

A

98-01-1

furfural

B

58-86-6

D-xylose

Conditions
ConditionsYield
With water In toluene at 170℃; for 6h; Inert atmosphere;A 18%
B 27%
With (2E)-but-2-enedioic acid In water at 160℃; for 4h; Reagent/catalyst; Temperature; Inert atmosphere; Autoclave; Industrial scale;A 24.4%
B 25.4%
22416-58-6

β-D-Xylp-(1-4)-β-D-Xylp-(1-4)-β-D-Xylp-(1-4)-β-D-Xyl

58-86-6

D-xylose

Conditions
ConditionsYield
With maize β-xylosidase for 6h; aq. acetate buffer; Enzymatic reaction;
With recombinant β-xylosidase/α-L-arabinofuranosidase/β-glucosidase from Cellulosimicrobium cellulans sp. 21 In aq. phosphate buffer at 30℃; for 0.166667h; pH=8; Enzymatic reaction;
Multi-step reaction with 2 steps
1: polyethylenimine-coated Selenomonas ruminantium β-xylosidase immobilized on glyoxyl agarose; water / aq. acetate buffer / 0.08 h / 50 °C / pH 5 / Enzymatic reaction
2: polyethylenimine-coated Selenomonas ruminantium β-xylosidase immobilized on glyoxyl agarose; water / aq. acetate buffer / 2 h / 50 °C / pH 5 / Enzymatic reaction
View Scheme
Ganoderma capense heteropolysaccharide GCPB-2, 1.03E5 Da

Ganoderma capense heteropolysaccharide GCPB-2, 1.03E5 Da

A

58-86-6

D-xylose

B

5328-37-0

L-arabinose

Conditions
ConditionsYield
With trifluoroacetic acid In water at 120℃; for 6h; Sealed tube;

β-D-xylopyranoside

A

58-86-6

D-xylose

B

472-11-7

(25R)-ruscogenin

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane; water at 95℃; for 1h; Inert atmosphere;A n/a
B 3.8 mg

phyllaemblicins H3

A

58-86-6

D-xylose

B

50-99-7

D-glucose

Conditions
ConditionsYield
With hydrogenchloride In water at 80℃; for 6h; Sealed tube;

phyllaemblicin H10

A

58-86-6

D-xylose

B

50-99-7

D-glucose

Conditions
ConditionsYield
With hydrogenchloride In water at 80℃; for 6h; Sealed tube;
47592-59-6

β-D-Xylp-(1-4)-β-D-Xylp-(1-4)-D-Xyl

58-86-6

D-xylose

Conditions
ConditionsYield
With recombinant β-xylosidase/α-L-arabinofuranosidase/β-glucosidase from Cellulosimicrobium cellulans sp. 21 In aq. phosphate buffer at 30℃; for 0.166667h; pH=8; Enzymatic reaction;
Multi-step reaction with 2 steps
1: polyethylenimine-coated Selenomonas ruminantium β-xylosidase immobilized on glyoxyl agarose; water / aq. acetate buffer / 2 h / 50 °C / pH 5 / Enzymatic reaction
2: polyethylenimine-coated Selenomonas ruminantium β-xylosidase immobilized on glyoxyl agarose; water / aq. acetate buffer / 2 h / 50 °C / pH 5 / Enzymatic reaction
View Scheme

(20S,24R)-(3α,12β)-20,24-epoxy-dammara-25-hydroxyl-12-O-β-D-quinovopyranoside-3-O-β-D-xylopyranoside

A

58-86-6

D-xylose

B

7658-08-4

D-quionovose

Conditions
ConditionsYield
With hydrogenchloride In water at 100℃; for 3h;
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Chemistry

Molecular Formula: C5H10O5
Molecular Weight: 150.13
EINECS: 200-400-7 
Index of Refraction: 1.646
Molar Refractivity: 31.02 cm3
Molar Volume: 85.4 cm3
Surface Tension: 75.3 dyne/cm
Density: 1.757 g/cm3
Flash Point: 155.3 °C
Enthalpy of Vaporization: 66.74 kJ/mol
Boiling Point: 333.2 °C at 760 mmHg
Vapour Pressure: 9.92E-06 mmHg at 25 °C
Melting point: 154-158 °C(lit.)
Storage tempreture: Store at RT.
Water solubility: 1 M at 20 °C, clear, colorless
Solubility: Soluble in water
Appearance: White crystals or powder
Structure of (D)-Xylose (CAS NO.58-86-6):
                      
IUPAC Name: (2S,3R,4S,5R)-Oxane-2,3,4,5-tetrol
Canonical SMILES: C1C(C(C(C(O1)O)O)O)O
Isomeric SMILES: C1[C@H]([C@@H]([C@H]([C@H](O1)O)O)O)O
InChI: InChI=1S/C5H10O5/c6-2-1-10-5(9)4(8)3(2)7/h2-9H,1H2/t2-,3+,4-,5+/m1/s1
InChIKey: SRBFZHDQGSBBOR-LECHCGJUSA-N
Product Category of (D)-Xylose (CAS NO.58-86-6): Basic Sugars (Mono & Oligosaccharides);Biochemistry;Xylose;Sweeteners;Carbohydrate Synthesis;Alphabetic;Food & Beverage Standards;CarbohydrateMetabolomics;Metabolic Libraries;Metabolic Pathways;Metabolites and Cofactors on the Metabolic Pathways Chart

Uses

 (D)-Xylose (CAS NO.58-86-6) is mainly used to prepare xylitol, and is also widely used in food processing andpharmaceutical industry. It can be used in food and beverage as a non-calorie sweetener, and it used for obesity and diabetes.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 11300mg/kg (11300mg/kg)   Yakkyoku. Pharmacy. Vol. 32, Pg. 1367, 1981.
mouse LD50 oral 23gm/kg (23000mg/kg)   Yakkyoku. Pharmacy. Vol. 32, Pg. 1367, 1981.

Consensus Reports

(D)-XYLOSE is reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 24/25-36-26
S24/25:Avoid contact with skin and eyes. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
WGK Germany: 2
RTECS: ZF2285000
F: 3
Hazard Note: Irritant
HS Code: 29400090
Hazardous Substances Data: 58-86-6(Hazardous Substances Data)
Slightly toxic by ingestion and intravenous routes. When heated to decomposition it emits acrid smoke and irritating vapors.

Specification

 (D)-Xylose , its cas register number is 58-86-6. It also can be called D(+)-Xylose ; Wood sugar ; and Xylose . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. And as soon as to get medical aid. Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately. Notes to physician: Treat supportively and symptomatically.
In addition, (D)-Xylose (CAS NO.58-86-6) could be stable under normal temperatures and pressures. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials, dust generation. And also prevent it to broken down into hazardous decomposition products: Carbon monoxide, carbon dioxide.