144-19-4Relevant articles and documents
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Herrmann
, p. 188 (1904)
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CATALYST AND METHOD FOR HYDROGENATION OF 1,3-CYCLOBUTANEDIKETONE COMPOUND
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Paragraph 0032, (2017/12/27)
Catalyst for hydrogenation of 1,3-cyclobutanediketone compound is provided, which includes a support and VIIIB group transition metal loaded thereon. The support includes a first oxide powder with a surface wrapped by a second oxide. The first oxide includes silicon oxide, aluminum oxide, zirconium oxide, titanium oxide, zinc oxide, or a combination thereof. The second oxide has a composition of MxAl(1-x)O(3-x)/2, M is alkaline earth metal, and x is from 0.3 to 0.7.
Method for simultaneous synthesis of 2,2,4-trimethyl-1,3-pentanediol diisobutyrate and 2,2,4-trimethyl-1,3-pentanediol
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Paragraph 0045; 0046; 0047; 0048, (2016/12/01)
The present invention relates to the field of fine chemicals, and in particular relates to a method for simultaneous synthesis of 2,2,4-trimethyl-1,3-pentanediol diisobutyrate and 2,2,4-trimethyl-1,3-pentanediol. The 2,2,4-trimethyl-1,3-pentanediol diisobutyrate and the 2,2,4-trimethyl-1,3-pentanediol can be obtained by transesterification of 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate under the effect of an acidic catalyst according to the method. A new method for synthesis of the 2,2,4-trimethyl-1,3-pentanediol diisobutyrate and the 2,2,4-trimethyl-1,3-pentanediol is provided, and according to the situation, product separation can be performed by ordinary distillation or reactive distillation. When the ordinary distillation is used for the product separation, 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate conversion rate is 45 to 60%. When the reactive distillation is used for the product separation, the 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate conversion rate is high and can reach 98 to 99%.