14986-21-1Relevant articles and documents
DIRECT MASS SPECTROMETRIC IDENTIFICATION OF SILICON OXYCHLORIDE COMPOUNDS.
Marra,Kreidler,Jacobson,Fox
, p. 1571 - 1574 (1988)
Silicon oxychloride compounds formed during the high temperature reaction of Si and SiC with Cl//2/O//2 mixtures at 930 degree and 950 degree C have been directly observed with an atmospheric pressure mass spectrometer sampling system. Molecules with the formulas Si//2OCl//6 and Si//3OCl//8 have been identified. These compounds are very likely formed by a gas phase reaction between the oxygen gas in the system and silicon tetrachloride which is produced by chlorination of the silicon-based material.
METHOD OF MAKING HALOSILOXANE
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Paragraph 0044-0046, (2019/01/06)
A method of producing a halosiloxane, the method comprising: combining water, a halosilane, and first solvent, where the first solvent has a water solubility of > 1.5 grams in 100 ml of solvent, to form a reaction mixture having a temperature above the melting point temperature of the solvent, partially hydrolyzing and condensing the halosilane to form a reaction product mixture comprising the halosiloxane, the solvent, a hydrogen halide and unreacted halosilane, and, optionally, adding a second solvent with a boiling point the boiling point of the halosloxane to the reaction mixture or the reaction product mixture.
A New Route to Linear and Cyclic Perchlorosiloxanes
Basenko, S. V.,Gebel', I. A.,Voronkov, M. G.,Klyba, L. V.,Mirskov, R. G.
, p. 314 - 315 (2008/10/09)
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