A possible mechanism for the Fe(Ⅲ)-catalysed Markovnikov hydrothiolation of styrenes is depicted
Iron-catalysed Markovnikov hydrothiolation of styrenes
Scheme 3
A possible mechanism for the Fe(Ⅲ)-catalysed Markovnikov hydrothiolation of styrenes is depicted in Scheme 3. This mechanistic proposal is based on the well-known capability of iron(Ⅲ) to activate concomitantly the benzylic position of double bondsizo] and soft nucleophiles toward additions.
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