The reactions of binucleophiles with EDG-substituted styrenes. 6

July 23, 2024

• Title:       

  The reactions of binucleophiles with EDG-substituted styrenes. 6

• Image Source:

  Mechanistic study of multi-step nucleophilic substitution for trifluoromethylated styrenes

• Mark:

  Scheme 6

• Associated context:

  Judging by their multiplicity and chemical shift values, a doublet at ꢀ46.6 ppm (3J (F, H) = 7.6 Hz) was assigned to enamine  6d and two triplets at -60.7 and -62.2 (3J (F, H) = 10.7 Hz) were attributed to its azomethine isomer 7c (Scheme 6). Then, a new triplet at -60.1 ppm (3J (F, H) = 11.4 Hz) appeared which was attributed to imidazolidine 9a.