The structure/electrochemical analyses of the diferrocene monothioacetates

August 13, 2024

• Title:       

  The structure/electrochemical analyses of the diferrocene monothioacetates

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  Ferrocene-based nanoelectronics Regioselective syntheses and electrochemical characterization of α-monothiol and α,ω- dithiol, phenylethynyl-conjugated, 2,5-diethynylpyridyl- And pyridinium-linked diferrocene frameworks having an end-to-end distance of ～4 nm

• Mark:

  Figure 5

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  Taken altogether,  these data allow for the structure/electrochemical analyses of the diferrocene monothioacetates presented in Figure 5A, in which a close correlation between the E1/2 values of 7 and 8 and those for the pairs of mono ferrocene model compounds, 28/45 and 29/46,  respectively, is observed. In particular, the DPV analyses for compound 8 and the corresponding mono ferrocene compounds 29  and 46 shown in Figure 5B clearly predict the presence of two one-electron redox couples with an ∆E1/2 value of approximately 50 mV in the diferrocene structure.