Journal of the American Chemical Society p. 1415 - 1418 (1986)
Update date:2022-08-02
Topics:
Zijl, P. C. M. van
Jenneskens, L. W.
Bastiaan, E. W.
MacLean, C.
Wolf, W. H. de
Bickelhaupt, F.
High field deuterium NMR provides a new and simple method for establishing the degree of aromaticity of a compound.The procedure is based on the determination of the magnetic susceptibility anisotropy from quadrupolar deuterium couplings of molecules in solution aligned by the magnetic field.The technique is illustrated for some deuterated dialkylbenzenes (2d, 3e, 4e) and applied to <8,11-2H2><5>metacyclophane (1d).Surprisingly, 1d is found to be fully aromatic in spite of its strongly bent benzene ring.
View MoreJinan Yijialian Economic and Trade Development Co., Ltd.
Contact:+86 0531-66729596
Address:jinan
Zouping Mingxing Chemical Co.,Ltd.
website:http://www.zoutong.com.cn
Contact:86-543-2240068 2240067
Address:428 Daixi Third Road Zouping County Shandong Province China
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)
Contact:+86-571-56880228
Address:15F Guodu development Building, NO.182 Zhaohui Road
Contact:+86-0512-69209969
Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.
Jiangsu Fengshan Group Co., Ltd.
Contact:86-25-86558671
Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China
Doi:10.1002/anie.200702440
(2007)Doi:10.1139/V07-131
(2008)Doi:10.1016/j.molcata.2006.10.035
(2007)Doi:10.1021/jo00358a036
(1986)Doi:10.1039/b712687e
(2007)Doi:10.1016/0022-328X(85)88040-2
(1985)
