Intramolecular palladium-catalyzed cyclization of alkenylboronate prepared from hydroboration of terminal acetylene and its application to the stereoselective synthesis of (E)-doxepin

DOI: 10.1016/j.tet.2007.09.085

Source and publish data:

Tetrahedron p. 248 - 254 (2008)

Update date:2022-07-29

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Authors:

Xue, Cuihua

Kung, Shi-Hao

Wu, Jian-Zhung

Luo, Fen-Tair

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Article abstract of DOI:10.1016/j.tet.2007.09.085

The hydroboration of 2-[(2-ethynylphenyl)methoxy]-1-iodobenzene with bis(pinacolato)diboron in the presence of palladium catalyst and followed by consecutive oxidative addition, cis-cyclocarbopalladation, and cis-β-elimination could give highly stereosele

Full text of DOI:10.1016/j.tet.2007.09.085

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Product name:2-({2-[(1E)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)vinyl]phenyl}methoxy)-1-iodobenzene

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