Inorganic Chemistry p. 1854 - 1859 (1967)
Update date:2022-07-30
Topics:
Jennings
Wojcicki, Andrew
The synthesis of and infrared spectral studies on rhodium(I) thiocyanato compounds of the types RhL2(CO)(NCS), RhL3(NCS), Rh2L4(CNS)2, and (R4N)[Rh(CO)2(NCS)2], where L is a phosphine, an arsine, a stibine, or a phosphite, are reported. In all of these complexes terminal thiocyanate is bonded through the nitrogen atom, both in the solid state and in solution. The arylarsine and phosphite thiocyanato derivatives dissociate in part in solution with the resultant formation of dinuclear, SCN-bridged complexes of the type Rh2(AsR3)2(CO)2(CNS)2 and Rh2[P(OR)3]4(CNS)2, respectively. The latter was isolated with triphenyl phosphite.
ChangZhou XiaQing Chemical Co., Ltd.
Contact:+86-519-88721665
Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
Chemtrade International ( China )
Contact:+86-532-86893005
Address:Rm 2-501, Huaxia Zonghe Building, No. 410 JInggangshan Road, Huangdao
website:http://www.NEM.COM.CN
Contact:+86-393-4411771
Address:The west section of shengli Road,Puyang,Henan Province,China
Shanghai Forever Synthesis Co.,Ltd.
Contact:021-61124658
Address:Zhoukang Road,Pudong New District,Shanghai,China
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.
Contact:15857995878 0579-82207761
Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
Doi:10.1002/ejoc.200700698
(2007)Doi:10.1016/S0008-6215(00)90852-8
(1988)Doi:10.1139/v81-110
(1981)Doi:10.1021/ja01516a054
(1959)Doi:10.1002/ejoc.201901858
(2020)Doi:10.1016/S0040-4039(00)94854-8
(1985)
