Inorganic Chemistry p. 1854 - 1859 (1967)
Update date:2022-07-30
Topics:
Jennings
Wojcicki, Andrew
The synthesis of and infrared spectral studies on rhodium(I) thiocyanato compounds of the types RhL2(CO)(NCS), RhL3(NCS), Rh2L4(CNS)2, and (R4N)[Rh(CO)2(NCS)2], where L is a phosphine, an arsine, a stibine, or a phosphite, are reported. In all of these complexes terminal thiocyanate is bonded through the nitrogen atom, both in the solid state and in solution. The arylarsine and phosphite thiocyanato derivatives dissociate in part in solution with the resultant formation of dinuclear, SCN-bridged complexes of the type Rh2(AsR3)2(CO)2(CNS)2 and Rh2[P(OR)3]4(CNS)2, respectively. The latter was isolated with triphenyl phosphite.
Zibo Xiaoguang Chemical Material Co., Ltd
Contact:15954099116
Address:Boshan Development Zone
Shanghai WinTide BioTechnology Co.,Ltd
Contact:86-21-37100630
Address:No. 908 Yunhe Road, Fengxian district, Shanghai
HK Vast Medicinal Chemistry Int'l Group Limited(expird)
website:http://www.hkvast.com/
Contact:+86-15000309979
Address:NO.6,Lane 108,Qinzhou Road,Xuhui District,Shanghai
Ceresking Ecology & Technology co.,ltd
Contact:86 22 66218397
Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.
KAIYUAN CHEMICAL COMPANY LIMITED.
website:http://www.kaiyuanchem.com
Contact:+86-22-59891255/66/77
Address:B-2205, Kuangshi International Building, Yingbin Road, XiangLuo Bay Business District, Binhai New area, Tianjin, China.
Doi:10.1002/ejoc.200700698
(2007)Doi:10.1016/S0008-6215(00)90852-8
(1988)Doi:10.1139/v81-110
(1981)Doi:10.1021/ja01516a054
(1959)Doi:10.1002/ejoc.201901858
(2020)Doi:10.1016/S0040-4039(00)94854-8
(1985)
