Journal of Organic Chemistry p. 2984 - 2988 (1991)
Update date:2022-09-26
Topics: Cycloaddition Intermolecular Approach Total syntheses Benzyne
Atanes, N.
Castedo, L.
Guitian, E.
Saa, C.
Saa, J. M.
Suau, R.
We describe a useful novel approach to the synthesis of aporphinoids, including dehydroaporphines, aristolactams, 4,5-dioxoaporphines, and 7-oxoaporphines, by means of intermolecular benzyne cycloaddition (IBC).Specifically, we report the total synthesis of the isoquinoline alkaloids norcepharadione B, cepharadione B, dehydroanonaine, deguenaine, dehydronornuciferine, pontevedrine, O-methylatheroline, lysicamine, and alkaloid PO-3.
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