TOTAL SYNTHESIS OF (+/-)-ALLIACOLIDE

DOI: 10.1016/S0040-4039(00)98750-1

Source and publish data:

Tetrahedron Letters p. 4413 - 4416 (1985)

Update date:2022-08-11

Topics:

Authors:

Ladlow, Mark

Pattenden, Gerald

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Article abstract of DOI:10.1016/S0040-4039(00)98750-1

A total synthesis of the unique epoxy-lactone alliacolide (3), featuring a novel, stereoselective intramolecular radical cyclisation onto an enolic double-bond, viz (13) ->(14), as a key step, is described.

Full text of DOI:10.1016/S0040-4039(00)98750-1

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Product name:(+/-)-1-epi-alliacolide

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