Regioselective Cycloadditions of N-Protonated Azomethine Ylides and 2-Azaallyl Anions Generated from N-(Silylmethyl) Thioimidates, Synthetic Equivalents of Nonstabilized Nitrile Ylides

DOI: 10.1021/jo00388a033

Source and publish data:

Journal of Organic Chemistry p. 2523 - 2530 (1987)

Update date:2022-08-02

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Authors:

Tsuge, Otohiko

Kanemasa, Shuji

Yamada, Toshiaki

Matsuda, Koyo

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Article abstract of DOI:10.1021/jo00388a033

A water-induced-desilylation method and a direct-desilylation method have been applied to N-(silylmethyl) thioimidates to lead to the generation of N-protonated azomethine ylides and 2-azaallyl anions, respectively.These reactive intermediates are capture

Full text of DOI:10.1021/jo00388a033

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