Synthesis of the Macrolactone Pyrrolizidine Alkaloid Integerrimine

DOI: 10.1021/jo00376a104

Source and publish data:

Journal of Organic Chemistry p. 5492 - 5494 (1986)

Update date:2022-09-26

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Authors:

White, James D.

Ohira, Susumu

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Article abstract of DOI:10.1021/jo00376a104

Synthesis of the natural enantiomer of the 12-membered dilactone integerrimine was accomplished by coupling retronecine with a masked version of integerrinecic acid.The latter was acquired in homochiral form from (R)-(-)-3-hydroxy-2-methylpropionate.

Full text of DOI:10.1021/jo00376a104

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