IMPROVED ENANTIOSELECTIVE SYNTHESIS OF ANTI α-METHYL-β-HYDROXYESTERS THROUGH TiCl4-PPh3 MEDIATED ALDOL CONDENSATION

DOI: 10.1016/S0040-4039(00)84360-9

Source and publish data:

Tetrahedron Letters p. 1735 - 1738 (1986)

Update date:2022-08-03

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Authors:

Palazzi, Camillo

Colombo, Lino

Gennari, Cesare

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Article abstract of DOI:10.1016/S0040-4039(00)84360-9

The complex between TiCl4 and PPh3 effectively catalyses the aldol addition of silyl ketene acetals to aldehydes dramatically improving the anti-syn ratios.

Full text of DOI:10.1016/S0040-4039(00)84360-9

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