Journal of the American Chemical Society p. 16132 - 16133 (2008)
Update date:2022-09-26
Topics: Enantioselective Reaction Auxiliary Removal Choose a Chiral Auxiliary
Igawa, Kazunobu
Takada, Junko
Shimono, Tomohiro
Tomooka, Katsuhiko
An enantioselective nucleophilic substitution reaction of achiral dialkoxysilane has been developed. The reaction proceeds with efficient stereocontrol on the silicon chirality center to give the enantioenriched silyl ether, which can be converted to the
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