Chemistry of Natural Compounds p. 36 - 42 (1991)
Update date:2022-08-03
Topics:
Koltsa, M. N.
Mironov, G. N.
Aryku, A. N.
Vlad, P. F.
The ozonolysis of a mixture of 13Z- and 13E-neoabienols (I and III) leads, depending on the conditions, either to 8α-hydroxy-14,15-bis-norlabd-11-en-13-one (IV) or to 8α-hydroxdriman-11-oic acid (VI) or to driman-8α,11-diol (VII).Compound (IV) undergoes hydrogenation smoothly with the formation of a mixture of 8α-hydroxy-14,15-bisnorlabdan-13-one (X) and "sclareol oxide" (XI).
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