Monomeric, three-coordinate tin(II) and lead(II) complexes with a MCP2 coordination sphere: Sn[CH(PPh2)2]2 and Pb[CH(PPh2)2]2

DOI: 10.1021/om00141a043

Source and publish data:

Organometallics p. 2159 - 2161 (1986)

Update date:2022-07-29

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Authors:

Balch, Alan L.

Oram, Douglas E.

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Article abstract of DOI:10.1021/om00141a043

Li[CH(PPh₂)₂] reacts with SnCl₂ or PbCl₂ in tetrahydrofuran to yield the homoleptic complexes Sn-[CH(PPh₂)₂]₂ or Pb[CH(PPh₂)₂]₂. X-ray crystallographic studies reveal similar structures with a monomeric, pyramidal MCP₂ core and two distinctly different bis(diphenylphosphino)methanide ligands.

Full text of DOI:10.1021/om00141a043

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