Asymmetric Synthesis of the Both Enantiomers of Tertiary Aryl Homoallyl Alcohols and Diols by Diastereoselective Addition of Allyltrimethylsilane to Chiral α-Keto Imides

DOI: 10.1246/cl.1987.341

Source and publish data:

Chemistry Letters p. 341 - 344 (1987)

Update date:2022-08-05

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Authors:

Soai, Kenso

Ishizaki, Miyuki

Yokoyama, Shuji

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Article abstract of DOI:10.1246/cl.1987.341

Both enantiomers of homoallyl-alcohols and -diols are obtained in high enantiomeric excess (91 -> 98 e.e.) by titanium tetrachloride promoted diastereoselective addition of allyltrimethylsilane to chiral α-keto imides.

Full text of DOI:10.1246/cl.1987.341

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