A Study of Asymmetric Induction during the Addition of Enolate Nucleophiles, Having Sulfoximine Chiral Auxiliaries, to Diene-Molybdenum and Dienyliron Complexes

DOI: 10.1021/ja00183a024

Source and publish data:

Journal of the American Chemical Society p. 134 - 144 (1989)

Update date:2022-08-05

Topics:

Authors:

Pearson, Anthony J.

Blystone, Sheri L.

Nar, Herbert

Pinkerton, A. Alan

Roden, Brian A.

Yoon, Jaeyon

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Article abstract of DOI:10.1021/ja00183a024

Asymmetric induction as high as 90percent ee was obtained during the reaction of enolates, derived from optically pure sulfoximinyl esters of type 16, with the cycloheptadiene-Mo(CO)2Cp cation.Lower, but still significant asymmetric induction was observed

Full text of DOI:10.1021/ja00183a024

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