Oxidative addition of O-H bond to a metal centre: synthesis and crystal structure of trans-(PhO)(H)Pd(PCy3)2*PhOH

DOI: 10.1016/0022-328X(87)80110-9

Source and publish data:

Journal of Organometallic Chemistry p. C46 - C48 (1987)

Update date:2022-08-04

Topics:

Authors:

Braga, Dario

Sabatino, Piera

Bugno, Cristina Di

Leoni, Piero

Pasquali, Marco

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Article abstract of DOI:10.1016/0022-328X(87)80110-9

(Cy3P)2Pd (Cy=C6H11) reacts with PhOH in toluene to give the phenoxopalladium(II) hydride derivative trans-(PhO)(H)Pd(PCy3)2*PhOH; the crystal structural study has established that the oxygen of the phenoxy group forms a hydrogen bridge with an uncoordinated phenol molecule, and has allowed direct location of the hydride atom (Pd-H, 1.57(2) Angstroem).

Full text of DOI:10.1016/0022-328X(87)80110-9

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