Journal of the Chemical Society, Dalton Transactions p. 275 - 278 (1985)
Update date:2022-08-03
Topics:
Tsuchida, Eishun
Nishide, Hiroyuki
Yuasa, Makoto
Hasegawa, Etsuo
Matsushita, Yoh-ichi
Eshima, Kiyoshi
A novel and amphiphilic 5,10,15,20-tetraphenylporphyrinatoiron complex substituted with phosphocholine groups, 5,10,15,20-tetra<α,α,α,α-o-<2',2'-dimethyl-20'-(2"-trimethylammonioethyl phosphonatoxy)eicosanamido>phenyl>porphyrinatoiron(II) (lipid-heme), has been synthesized.The lipid-heme formed a stable liposome with a phospholipid.The liposomal lipid-heme reversibly bound oxygen in neutral aqueous media at 37 deg C, and its oxygen-binding rate and affinity were similar to those of red blood cells.
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