
Journal of the American Chemical Society p. 1164 - 1171 (1990)
Update date:2022-07-31
Topics:
Ihara, Masataka
Suzuki, Makoto
Fukumoto, Keiichiro
Kabuto, Chizuko
The bridged, pentacyclic intermediate 2 for atisine (1) was synthesized in a naturally occurring enantiomeric form from dimethyl cyclohexanone-2,6-dicarboxylate (6). The synthesis is composed of the following key steps: (1) formation of the azabicyclo[3.3
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