Tetrahedron Letters p. 1299 - 1302 (1987)
Update date:2022-08-02
Topics:
Matsuoka, Rikitaro
Horiguchi, Yoshiaki
Kuwajima, Isao
A 3-(t-butyldimethylsiloxy)allenlyllithium generated quantitatively from the 1-silylpropargyl alcohol can be used as a synthetic equivalent of α,β-unsaturated ketone having nucleophilic center at its β-position through transmetallation.
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