Synthesis of (Diethoxyphosphoryl)acetonitrile Oxide and Its Cycloaddition to Olefins. Synthetic Applications to 3,5-Disubstituted 2-Isoxazolines

DOI: 10.1246/bcsj.60.2463

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2463 - 2474 (1987)

Update date:2022-08-02

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Authors:

Tsuge, Otohiko

Kanemasa, Shuji

Suga, Hiroyuki

Nakagawa, Norihiko

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Article abstract of DOI:10.1246/bcsj.60.2463

(Diethoxyphosphoryl)acetonitrile oxide undergoes regioselective cycloaddition to olefins leading to 3-<(diethoxyphosphoryl)methyl>-2-isoxazolines or -isoxazole.The phosphorus-stabilized carbanions generated by deprotonation of the cycloadducts can be util

Full text of DOI:10.1246/bcsj.60.2463

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