133. Nucleophilic Additions to N-Glycosylnitrones. Part IV. Asymmetric Synthesis of N-Hydroxy-α-aminophosphonic and α-Aminophosphonic Acids

DOI: 10.1002/hlca.19870700603

Source and publish data:

Helvetica Chimica Acta p. 1461 - 1476 (1987)

Update date:2022-08-03

Topics:

Authors:

Huber, Rolf

Vasella, Andrea

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19870700603

The addition of phosphite anions and of tris(trimethylsilyl)phosphite (P(OSiMe3)3) to N-glycosyl-C-aryl-nitrones was examined.While these nitrones proved inert towards the phosphite anions, they reacted with P(OSiMe3)3 under catalysis by Lewis acids.Thus,

Full text of DOI:10.1002/hlca.19870700603

Products guided by the article

Product name:(RS)-phosphonic acid

Cas No:114987-76-7

R&D Labs maybe for 114987-76-7

Zhejiang Kangfeng Chemical Co.,LTD.

Contact:+86-579-86709687

Address:Xueshizhai Industrial Zone, Weishan Town,Dongyang City, Zhejiang Province ,China
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD

Contact:29-63685658 63685359

Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
Jinan Jinguilin Chemical Co.,Ltd

Contact:+86-531-81188412

Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China

Relevant to this article

A Horner-Wittig synthesis of 1-chlorovinyl sulfoxides

Doi:10.1080/10426509608545187
(1996)
Regioselective synthesis of partially protected trehalose analogues and assignment of ring size in isopropylidene acetal derivatives by ¹³C NMR spectroscopy

Doi:10.1080/07328309608005683
(1996)
Photochemically generated cyclopentane-1,3-diyl triplet diradicals as model systems for the assessment of spin delocalization in heteroaryl-substituted benzyl-type monoradicals through the EPR spectral D parameter

Doi:10.1039/a607513d
(1997)
Energetics of a low barrier hydrogen bond in nonpolar solvents

Doi:10.1021/ja960288l
(1996)
Amino acid based diastereoselective synthesis of elsaminose

Doi:10.1016/0040-4039(96)01173-2
(1996)
Tandem hydroformylation/acyloin reaction - The synergy of metal catalysis and organocatalysis yielding acyloins directly from olefins

Doi:10.1002/adsc.201401031
(2015)

Article Doi