133. Nucleophilic Additions to N-Glycosylnitrones. Part IV. Asymmetric Synthesis of N-Hydroxy-α-aminophosphonic and α-Aminophosphonic Acids

DOI: 10.1002/hlca.19870700603

Source and publish data:

Helvetica Chimica Acta p. 1461 - 1476 (1987)

Update date:2022-08-03

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Authors:

Huber, Rolf

Vasella, Andrea

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Article abstract of DOI:10.1002/hlca.19870700603

The addition of phosphite anions and of tris(trimethylsilyl)phosphite (P(OSiMe3)3) to N-glycosyl-C-aryl-nitrones was examined.While these nitrones proved inert towards the phosphite anions, they reacted with P(OSiMe3)3 under catalysis by Lewis acids.Thus,

Full text of DOI:10.1002/hlca.19870700603

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