Ligating properties of thionitrosoamines. IV. Cationic complexes of rhodium(I), rhodium(III), and ruthenium (II) containing N-thionitrosodimethylamine

DOI: 10.1016/0022-328X(87)80254-1

Source and publish data:

Journal of Organometallic Chemistry p. 387 - 392 (1987)

Update date:2022-07-30

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Authors:

Tresoldi, Giuseppe

Sergi, Sergio

Schiavo, Sandra Lo

Piraino, Pasquale

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Article abstract of DOI:10.1016/0022-328X(87)80254-1

The solvent species obtained by treatment of the complexes 2, 2, 2, C5H5Rh(CO)I2, 2, and 2 with AgPF6 in acetone or acetonitrile react with a large excess of Me2NNS to give

Full text of DOI:10.1016/0022-328X(87)80254-1

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Product name:Rh(C₈H₁₂)(SNN(CH₃)2)(P(C₆H₅)3)⁽¹⁺⁾*ClO₄^(1-)=(Rh(C₈H₁₂)(SNN(CH₃)2)(P(C₆H₅)3))ClO₄

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