Phosphorverbindungen ungewoehnlicher Koordination. XXV. Cyclopropenyl-phosphaalkene, Edukte zur Synthese stabiler 2H-Phosphole

DOI: 10.1016/0022-328X(87)85141-0

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C5 (1987)

Update date:2022-08-03

Topics:

Authors:

Zurmuehlen, Frank

Regitz, Manfred

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Article abstract of DOI:10.1016/0022-328X(87)85141-0

Reaction of a cyclopropenylium salt with lithium bis(trimethylsilyl)phosphide*2THF yields a phosphinocyclopropene.Replacement of a trimethylsilyl group by lithium followed by acylation with acid chlorides and relocation of silyl group leads to cyclopropen

Full text of DOI:10.1016/0022-328X(87)85141-0

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