Anti Stereochemistry in SE'' Reaction of an Optically Active 2,4-Dienylsilane

DOI: 10.1246/cl.1987.2037

Source and publish data:

Chemistry Letters p. 2037 - 2040 (1987)

Update date:2022-07-31

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Authors:

Hayashi, Tamio

Matsumoto, Yonetatsu

Ito, Yoshihiko

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Article abstract of DOI:10.1246/cl.1987.2037

The S_E'' reaction of (S)-(3E,5E)-2-(trimethylsilyl)hepta-3,5-diene with acetyl chloride and aluminium chloride in dichloromethane proceeded with anti stereochemistry to give (2Z,4E)-6-methylocta-2,4-dien-7-one of R configuration and its (2E,4E)

Full text of DOI:10.1246/cl.1987.2037

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