Reactions of Methyl(2,5,5-trimethyl-1-cyclopenten-1-yl)carbene and the Photochemistry of 2-(1-Propenyl)-2,5,5-trimethylcyclopentanone

DOI: 10.1021/jo00076a022

Source and publish data:

Journal of Organic Chemistry p. 6629 - 6633 (1993)

Update date:2022-08-04

Topics:

Authors:

Venugopal, D.

Margaretha, Paul

Agosta, William C.

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Article abstract of DOI:10.1021/jo00076a022

Dienes 7 and 8 are formed both on photolysis of 1 and on triplet decomposition of diazo compound 14.These observations appear to imply that biradical 3, a photochemical intermediate formed from 1, closes to carbene 9, from which 7 and 8 result on migratio

Full text of DOI:10.1021/jo00076a022

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