Reactions of Methyl(2,5,5-trimethyl-1-cyclopenten-1-yl)carbene and the Photochemistry of 2-(1-Propenyl)-2,5,5-trimethylcyclopentanone

DOI: 10.1021/jo00076a022

Source and publish data:

Journal of Organic Chemistry p. 6629 - 6633 (1993)

Update date:2022-08-04

Topics:

Authors:

Venugopal, D.

Margaretha, Paul

Agosta, William C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00076a022

Dienes 7 and 8 are formed both on photolysis of 1 and on triplet decomposition of diazo compound 14.These observations appear to imply that biradical 3, a photochemical intermediate formed from 1, closes to carbene 9, from which 7 and 8 result on migratio

Full text of DOI:10.1021/jo00076a022

Products guided by the article

Product name:1,3,3-Trimethyl-2-vinyl-1-cyclopentene

Cas No:117154-84-4

R&D Labs maybe for 117154-84-4

EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
Shanghai Yingrui Biopharma Co., Ltd

Contact:021-3358 8661*8003

Address:shanghai
Shenzhen JYMed Technology Co.,Ltd.

website:http://www.jymedtech.com

Contact:+86-755-26612112

Address:1#8,9/F, Biomedicine innovation Industrial Park, No.14, Jinhui Road, Pingshan Sistrict, Shenzhen, China
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China

Relevant to this article

Doi:10.1016/S0040-4039(01)83802-8
(1977)
Base-Induced Cyclization of Active Methylene Isocyanides with Xanthate Esters: An Efficient Method for the Synthesis of 5-Alkoxy-4-(tosyl/ethoxycarbonyl)-1,3-thiazoles

Doi:10.1055/s-0036-1590811
(2017)
Probing the Hydrophobic Binding Pocket of G-Protein-Coupled Lysophosphatidylserine Receptor GPR34/LPS₁ by Docking-Aided Structure-Activity Analysis

Doi:10.1021/acs.jmedchem.7b00693
(2017)
Carboxylate-directed highly stereoselective homogeneous hydrogenation of cyclic olefins with Wilkinson's catalyst

Doi:10.1021/ol034464o
(2003)
Direct formation of 4-alkoxy derivatives from 2,5-dimethyl-4-hydroxy-3(2H)-furanone and aliphatic alcohols

Doi:10.1021/jf950451g
(1996)
Doi:10.1021/ja01648a074
(1954)

Article Doi