SYNTHESIS AND THERMAL REARRANGEMENT OF 5-DIAZOMETHYL-1,2,3-TRIAZOLES

DOI: 10.1016/S0040-4020(01)85837-3

Source and publish data:

Tetrahedron p. 461 - 470 (1988)

Update date:2022-08-02

Topics: Synthesis Thermal Rearrangement

Authors:

L'Abbe, Gerrit

Dehaen, Wim

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Article abstract of DOI:10.1016/S0040-4020(01)85837-3

5-Diazomethyl-4-methoxycarbonyltriazoles are capable of undergoing ring-degenerate rearrangements (19+20) when a strong electron withdrawing substituent (e.g. p-nitrophenyl or o,p-dinitrophenyl) is located at the N-1 position.Whereas the unrearranged diaz

Full text of DOI:10.1016/S0040-4020(01)85837-3

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