A New Propargylic Rearrangement of Acetylenic Alcohols by P4S10. A New Preparative Method for Monothio-α-diketone

DOI: 10.1246/cl.1987.1299

Source and publish data:

Chemistry Letters p. 1299 - 1300 (1987)

Update date:2022-08-03

Topics:

Authors:

Toda, Fumio

Tokunaga, Yasuyuki

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Article abstract of DOI:10.1246/cl.1987.1299

Treatment of acetylenic alcohols with phosphorus pentasulfide P4S10 at room temperature gave thioketones.Similarly, treatment of acetylenic alcohol having a carbonyl group on its acetylenic carbon gave monothio-α-diketone.It was clarified that four sulfur

Full text of DOI:10.1246/cl.1987.1299

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